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to take account of all the types of mixed units in them. The problem is somewhat simpler in the case of cluster-containing monomers that are obtained on interaction of ligands with individual clusters, which are capable of polymerization transformations. For example, the reaction of the carbonyl cluster Rh6(CO)16-4-ViPy system in the presence of trimethylamine N-oxide under mild conditions a ords the monosubstituted derivative Rh6(CO)15(4-ViPy) as a major product and disubstituted compound, Rh6(CO)14(4-ViPy)2, in a relatively low yield.137 These two species can be isolated in a pure state by chromatography. The vinyl group in these MCMs lies in the plane of the pyridine fragment and does not interact with the rhodium cluster. In the case of Rh4(CO)12 and 4-ViPy, nonselective polysubstitution of the CO groups occurs and results in a number of products in relatively low yields. Thus the problem involved in the synthesis and subsequent polymerization of MCMs of this type is to introduce selectively speci c ligands with retention of the noncoordinated double bond. Since the IR spectra in the region of vibrations of the cluster carbonyl groups provide a great deal of information, these spectra are used for elucidation of the nuclearity of metal-containing sites in polymers. Yet another speci c feature namely, the formation of a cluster with the orthometallated 4-ViPy ligand was noted in a study of the triosmium carbonyl cluster.138,139 In this case, the replacement of a CO group by PPh3 made it possible to prepare the phosphine derivative of the MCMs (scheme 30). crystal reports barcode font encoder ufl Crystal Reports Barcode Font UFL | Tutorials - IDAutomation This encoder is free to use with any IDAutomation barcode font package and supports linear ... 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